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Thinkin Ink

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The truth is?you can't be 100% sure! Producers of pigments and inks are not obligated to divulge the ingredients of their products. Pigments and tattoo inks are not regulated by the US Food and Drug Administration. An artist who mixes their own inks from dry pigments would be most likely to know the exact formulation of the inks. Keep in mind the information is usually proprietary (a trade secret), so you may or may not get answers to your questions.



Most tattoo inks technically are not inks at all. They are a composition of pigments that are suspended in a carrier solution. Contrary to popular belief, pigments are generally not vegetable dyes. Modern pigments primarily consist of metal salts. In addition, some pigments contain plastics and there are some vegetable dyes as well. The pigment provides the color and the carrier disinfects the pigment suspension, keeps it evenly mixed, and accommodates ease of application.

The Chemistry of Pigments

The ancients made pigments from grinding up minerals and carbon black. Today's pigments include the original mineral pigments, modern industrial organic pigments, a few vegetable-based pigments, in addition to some plastic-based pigments. Allergic reactions, scarring, phototoxic reactions (reaction from exposure to light, especially sunlight), and other negative reactions are a possibility with various pigments. The plastic-based pigments are intensely colored, but many people have reported allergic reactions following its use. There are also pigments that luminesce (glow in the dark) when exposed to black (ultraviolet) light. These pigments are risky? some may be safe, but others can actually be radioactive or toxic in other dreadful ways.

Here's a listing of common pigments use in tattoo inks. It's not very extensive?remember?pretty much anything that can be used as a pigment has been at one time or another. And, many inks may mix one or more pigments.

Compostion of Tattoo Pigments

Pigment:

Black

Composition:

Iron Oxide (Fe3O4)

Iron Oxide (FeO)

Carbon

Comments:

Natural black pigment is made from

magnetite crystals, powdered jet,

wustite, bone black,and amorphous

carbon from combustion (soot).

Black pigment is commonly made

into India ink.

Logwood is a heartwood extract

from Haematoxylon campechisnum,

found in Central America and

the West Indies.

Pigment:

Brown

Composition:

Ochre

Comments:

Ochre is composed of iron (ferric)

oxides mixed with clay. Raw ochre

is yellowish. When dehydrated

through heating, ochre changes

to a reddish color.

Pigment:

Red

Composition:

Cinnabar (HgS)

Cadmium Red (CdSe)

Iron Oxide (Fe2O3)

Napthol-AS pigment

Comments:

Iron oxide is also known as common rust.

Cinnabar and cadmium pigments are

highly toxic. Napthol reds are synthesized

from Naptha. Fewer reactions have been

reported with naphthol red than the other

pigments, but all reds carry risks of allergic

or other reactions.

Pigment:

Orange

Composition:

Disazodiarylide

and/or Disazopyrazolone

Cadmium seleno-sulfide

Comments:

The organics are formed from the

condensation of 2 monoazo pigment

molecules. They are large molecules

with good thermal stability and colorfastness.

Pigment:

Flesh

Composition:

Ochres (iron oxides mixed with clay)

Comments:

None

Pigment:

Yellow

Composition:

Cadmium Yellow (CdS, CdZnS)

Ochres

Curcuma Yellow

Chrome Yellow (PbCrO4, often mixed with PbS)

Disazodiarylide

Comments:

Curcuma is derived from plants of

the ginger family; aka tumeric or curcurmin.

Reactions are commonly associated with

yellow pigments, in part because more

pigment is needed to achieve a bright color.

Pigment:

Green

Composition:

Chromium Oxide (Cr2O3), called

Casalis Green or Anadomis Green

Malachite [Cu2(CO3)(OH)2]

Ferrocyanides and Ferricyanides

Lead chromate

Monoazo pigment

Cu/Al phthalocyanine

Cu phthalocyanine

Comments:

The greens often include admixtures,

such as potassium ferrocyanide

(yellow or red) and

ferric ferrocyanide (Prussian Blue)

Pigment:

Blue

Composition:

Azure Blue

Cobalt Blue

Cu-phthalocyanine

Comments:

Blue pigments from minerals include

copper (II) carbonate (azurite), sodium

aluminum silicate (lapis lazuli),

calcium copper silicate (Egyptian Blue),

other cobalt aluminum oxides and

chromium oxides. The safest blues and

greens are copper salts, such as copper

pthalocyanine. Copper pthalocyanine

pigments have FDA approval for use in

infant furniture and toys and contact lenses.

The copper-based pigments are

considerably safer or more stable

than cobalt or ultramarine pigments.

Pigment:

Violet

Composition:

Manganese Violet

(manganese ammonium pyrophosphate)

Various aluminum salts

Quinacridone

Dioxazine/carbazole

Comments:

Some of the purples, especially the

bright magentas, are photoreactive and

lose their color after prolonged exposure

to light. Dioxazine and carbazole result

in the most stable purple pigments.

Pigment:

White

Composition:

Lead White (Lead Carbonate)

Titanium dioxide (TiO2)

Barium Sulfate (BaSO4)

Zinc Oxide

Comments:

Some white pigments are derived from

anatase or rutile. White pigment may be

used alone or to dilute the intensity of

other pigments. Titanium oxides are one

of the least reactive white pigments.

Tattoo ink is made up of pigment and a carrier. The carrier may be a single material or a mixture. The function of the carrier is to keep the pigment evenly distributed in a fluid matrix, to inhibit the introduction of pathogens, to prevent the clumping of pigment, as well as aiding in application to the skin itself. Some common components used to make the carrier are:

* ethyl alcohol (ethanol)

* purified water

* witch hazel

* Listerine

* propylene glycol

* glycerine (glycerol)

However, a laundry list of other stuff has been and may be used, including:

* denatured alcohols (toxic and can burn the skin)

* other alcohols (methyl alcohol or methanol and isopropyl alcohol or rubbing alcohol are sometimes used, even though they are toxic)

* ethylene glycol (antifreeze, very toxic)

* aldehydes, for example, formaldehyde and gluteraldehyde (highly toxic)

* various surfactants or detergents

There are several other substances that may be found in an ink. An artist has the option of mixing their own ink (dry dispersed pigment and a carrier solution) or purchasing predispersed pigments. Many predispersed pigments are as safe or safer than inks mixed by the individual tattooist. However, the exact ingredients need not be disclosed, so any chemical could be present in the ink. The prudent thing to do would be to ask your artist if the ink supplier and the particular ink has a history of safety. Remember, although the term toxic has been associated with some substances mentioned in the pigments and carriers, it is a gross understatement. Some of these compounds are mutagens, carcinogens, teratogens, toxins, or can cause other adverse symptoms, some of which may not manifest themselves for years.

Arm yourself with knowledge and ask the right questions of a tattoo professional. This will ensure you a safe and rewarding tattooing experience in addition to developing a rapport with your artist, an important factor for future advise or tattoos.
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